Exercise Files
BROCHURE
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INTRODUCTORY CLASS
Introducing the IIT-JAM Chemistry Course structure to the students
Syllabus Discussion
Time Table for the Month of October
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MODULE 1 : SOLID STATE
Crystals and crystal systems; X-rays; NaCl and KCl structures; close
packing; atomic and ionic radii; radius ratio rules; lattice energy; Born-Haber cycle;
isomorphism; heat capacity of solids.
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MODULE 2 : PERIODIC TABLE
Periodic classification of elements and periodicity in properties; general methods of isolation purification of elements.
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MODULE 3 : CHEMICAL BONDING AND SHAPES OF COMPOUNDS:
Types of bonding; VSEPR theory and shapes molecules; hybridization; dipole moment; ionic solids; structure of NaCl, CsCl, diamond and graphite; lace energy
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QUIZ
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MODUEL 8 : s AND p BLOCK ELEMENTS
General concepts on group relationships and gradation in properties; structure electron deficient compounds involving main group elements.
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MODULE 4 : ATOMIC AND MOLECULAR STRUCTURE
Fundamental particles; Bohr’s theory of hydrogen-like atom; wave-particle dual uncertainty principle; Schrödinger’s wave equation; quantum numbers; shapes of orbitals; Hund’s rule and Pauli’s exclusion principle; electronic configuration of simple homonuclear diatomic molecules.
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MODULE 5 : CHEMICAL KINETICS
Reactions of various order; Arrhenius equation; collision theory; transition state theory; chain reactions – normal and branched; enzyme kinetics; photochemical processes; catalysis
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MODULE 6 : CHEMICAL ADSORPTION
Gibbs adsorption equation; adsorption isotherm; types of adsorption; surface area of adsorbents; surface fi on liquids
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MODULE 7 : BASIC ORGANIC CHEMISTRY
Electronic effects (resonance, inductive, hyper conjugation) steric effects and its applications (acid/base property); optical isomerism in compounds with and without any stereocenters (allenes, biphenyls); conformation of acyclic systems (substituted ethane/n-propane/nbutane) and cyclic systems (mono and di-substituted cyclohexanes). Organic
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MODULE 9 : HETEROCYCLIC CHEMISTRY
MONOCYCLIC, BICYCLIC AND TRICYCLIC AROMATIC HYDROCARBONS, AND MONOCYCLIC COMPOUNDS WITH ONE HETERO ATOM: SYNTHESIS, REACTIVITY AND PROPERTIES.
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MODULE 10: CHEMISTRY OF NATURAL PRODUCTS
CHEMISTRY OF ALKALOIDS, STEROIDS, TERPENES, CARBOHYDRATES, AMINO ACIDS, PEPTIDES AND NUCLEIC ACIDS
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MODULE 11 :ELECTROCHEMISTRY
Conductance and its applications; transport number; galvanic cells; EMF and free energy; concentration cells with and without transport; polarography; concentration cells with and without transport; Debey-Huckel-Onsagar theory of strong electrolytes.
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MODULE 12 :CHEMICAL THERMODYNAMICS
Reversible and irreversible processes; first law and its application to ideal and non ideal gas thermochemistry; second law; entropy and free energy; criteria for spontaneity.
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MODULE 13 : ORGANIC REACTION MECHANISM AND SYNTHETIC APPLICATIONS
Chemistry of reactive intermediates (carbocations, carbanion free radicals, carbenes, nitrenes, benzynes etc…); Hofmann-Curtius-Lossen rearrangement, Wolff rearrangement, Simmons Smith reaction, Reimer-Tiemann reaction, Michael reaction, Darzens reaction, Wittig reaction and McMurry reaction Pinacol-pinacolone, Favorskii, benzilic acid rearrangement, dienone-phenol rearrangement, Baeyer-Villeger reaction oxidation and reduction reactions in organic chemistry; organometallic reagents in organic synthesis (Grignard organolithium and organocopper); Diels-Alder, electrocyclic and sigma tropic reactions; functional group inter-conversion and structural proble
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MODULE 14:COORDINATION CHEMISTRY
coordination complexes: structure, isomerism, reaction mechanism and electronic spectra; VB, MO and Crystal Field theoretical approaches
for structure, color and magnetic properties of metal complexes; organometallic compounds having liga with back bonding capabilities such as metal carbonyls, carbenes, nitrosyls and metallocenes; homogenous catalysis
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MODULE 15 : CHEMICAL AND PHASE EQULIBRIA
Law of mass action; Kp, Kc, Kx and Kn; effect of temperature on K; ionic equilibria solutions; pH and buffer solutions; hydrolysis; solubility product; phase equilibria–phase rule and its application to one component and two-component systems; colligative properties
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MODULE 16 : TRANSITION METALS
Characteristics of 3d elements; oxide, hydroxide and salts of first row metals
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MODULE 17 : INSTRUMENTAL METHODS OF ANALYSIS
Basic principles; instrumentations and simple applications of conductometry, potentiometry and UV-vis spectrophotometry; analysis of water, air and soil samples.
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MODULE 18 : ANALYTICAL CHEMISTRY
Principles of qualitative and quantitative analysis; acid-base, oxidation-reduction complexometric titrations using EDTA; precipitation reactions; use of indicators; use of organic reagents in inorganic analysis; radioactivity; nuclear reactions; applications of isotopes.
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MODULE 19 : SPECTROSCOPY
Beer-Lambert law; fundamental concepts of rotational, vibrational, electronic and magnetic resonance spectroscopy.
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MODULE 20 : STEREOCHEMISTRY
optical isomerism in compounds with and without any stereocenters (allenes, biphenyls); conformation of acyclic systems (substituted ethane/n-propane/nbutane) and cyclic systems (mono and di-substituted cyclohexanes).
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MODULE 21 : ORGANIC REACTION MECHANISMS
Hofmann-Curtius-Lossen rearrangement, Wolff rearrangement, Simmons Smith reaction, Reimer-Tiemann reaction, Michael reaction, Darzens reaction, Wittig reaction and McMurry reaction Pinacol-pinacolone, Favorskii, benzilic acid rearrangement, dienone-phenol rearrangement, Baeyer-Villeger reaction oxidation and reduction reactions in organic chemistry
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